“You can press it as much as you want. While flexible and stretchable electronics already exist, the insensitivity to shock and
impact are somewhat new”
Dr. Max Hamedi, who is a researcher at KTH and Harvard
University commenting on the developement of an aerogel battery based on
cellulose derived from wood
I already know it's possible to make a water filter
that can remove harmful E.Coli Bacteria using a Tree Branch cutting as reported
in my blog
article entitled “MIT
Researchers use White Pine Tree Branches as effective Water Filter - How to
make Potable Water using a Xylem Filter”.
But batteries? Never saw that coming!
An international research team from the KTH Royal
Institute of Technology from Sweden and Stanford University in the USA have
developed a high-capacity aerogel battery based on wood pulp as reported in the
article “Trees
are source for highcapacity, soft batteries”, published June 1 2015, Physorg.
Their research was published in the Friday May 9th
2015 issue of Nature Communications
magazine under the heading titled “SelfAssembled ThreeDimensional
And Compressible Interdigitated Thin Film Supercapacitors And Batteries”.
The cellulose battery marks a departure away from
making batteries from traditional inorganic material with an emphasis on making
the battery conform to a particular shape.
Instead, thanks to the flexible and compressible
nature of wood pulp, it is possible to make the battery any shape and then
squeeze it into any space and it still retains its energy-storage properties to
quote Dr. Max Hamedi, who is a researcher at KTH and Harvard University: “It is
possible to make incredible materials from trees and cellulose. There are
limits to how thin a battery can be, but that becomes less relevant in 3D. We
are no longer restricted to two dimensions. We can build in three dimensions,
enabling us to fit more electronics in a smaller space”.
This is the 3D Structure that Dr. Max Hamedi is
gushing about, as normally most batteries are constructed by mixing together
and inorganic compounds to make the paste inside of most typical batteries, a
process that can be likened to 2D.
This cellulose battery’s made from a material that
is already 3D in nature.
Chemicals have been added to give it the properties
for a very high capacity battery that's soft as mattress foam but just as
unbreakable, to quote Dr. Max Hamedi: “The result is a material that is strong,
light and soft. The material resembles
foam in a mattress, though it is a little harder, lighter and more porous. You
can touch it without it breaking”.
We may be looking at yet another high capacity
battery that can be used in Alternative Energy Applications like the University
of Texas at Austin Semi-Liquid Battery as detailed in my blog article entitled
“University
of Texas at Austin Semi-Liquid Battery – Liquid Gel Batteries in Smartphones
means Battery life measured in years and not hours” and possibly Tablets
and smartphones.
So how did Dr. Max Hamedi and the research team from
the KTH Royal Institute of Technology from Sweden and Stanford University in
the USA fabricate this battery? First, they had to cut some wood.
Dr.
Max Hamedi cellulose Aerogel Battery - Tetrahedral crystalline structure Serta
Mattress
The researchers got some wood from select trees,
removed the bark and then proceeded to masticate the wood until it was a powder
on the same level of purity as baking flour.
This reduced the macromolecular structure of the cellulose
to one where it composed of anywhere from 20 to 200 atoms in molecular chains,
effectively making the cellulose into a nano-material. Those nano-particles of
cellulose were then dissolved in boiled distilled water, which was then frozen
slowly so create large ice crystal forming without any dissolved gases.
Then the frozen nano-particles of cellulose were
freeze-dried using a vacuum evaporator set at high vacuum, causing the water to
sublime from a solid phase straight to a gaseous phase.
Because the frozen ice did not pass through a water
phase, which would have occurred had the frozen nano-particles of cellulose
been melted at r.t.p (Room temperature and pressure), the nano-particles of
cellulose remained locked in the tetrahedral crystalline structure made up of hydrogen
bonds that was formed by the ice crystals.
This meant that the nano-particles of cellulose now
had a macromolecular tetrahedral crystalline structure like a diamond.
But because it was composed of nano-particles of
cellulose held together by Van Der Waal's bonds and possibly some covalent
bonds due to the high reactivity of the nano-particles of cellulose, the
structure isn't so rigid and is comparable in surface area to the human lung, to
quote Dr. Max Hamedi: “You can press it as much as you want. While flexible and
stretchable electronics already exist, the insensitivity to shock and impact
are somewhat new."
In fact, it is porous and sponge-like properties are
because of the air pockets left by the smaller water molecules that were
freeze-dried out of the molecular matrix. The result is an air-filled form of
cellulose mimicking an aerogel. It was then treated with metallic salts
containing Lithium, Vanadium. Manganese and Zinc using vapour deposition.
The result: an aerogel that can store energy within
its honeycomb-like tetrahedral crystalline structure like a battery to quote Dr.
Max Hamedi: “We use a very precise technique, verging on the atomic level,
which adds ink that conducts electricity within the aerogel. You can coat the
entire surface within”.
Or, a really comfortable alternative to the Serta
Mattress that’s got power storage as an option for your smartphone!
3D
Batteries made from Cellulose – Smartphone and All-Electric Vehicles Battery
life measured in years
I actually though this battery was going to be a bit
impractical, as there would be no way to graft a metallic electrode unto an
organic aerogel made from a natural organic polymer like cellulose.
But again the research team from the KTH Royal
Institute of Technology from Sweden and Stanford University in the USA has
apparently figured out how to graft metallic conductors unto the organic
aerogel, possibly by using vapor depositing to build up the electrode one layer
at a time to connect with the previously vapour deposited Metallic salts.
To quote Dr. Max Hamedi, this was no problem, quote:
“Threedimensional, porous materials have been regarded as an obstacle to
building electrodes. But we have proven that this is not a problem. In fact,
this type of structure and material architecture allows flexibility and freedom
in the design of batteries”.
This means that this aerogel battery based on
cellulose can be used in applications where a high capacity battery is needed
but with a lower weight and also taking up less space. Good examples include
All-Electric Vehicles, Laptops, Smartphones, Tablets and yes, even in space
exploration on the ISS (International Space Station).
The Sweden-based Mars One Program to put colonists
on Mars reality-television style by 2045 may also benefit as noted in my blog article entitled
“@MIT
Study on Mars One - Why Staying Alive for 68 Days Eating Vegetables means
Oxygen has a License to Kill”.
Such compressible batteries would reduce the weight
of their payload while storing electrical energy to be used by the four (4)
initial colonists.
More reason to save the trees, as potentially they
can not only provide clean, bacteria free drinking water but herald the
next-generation of high capacity 3D Compressible Batteries for smartphones,
Tablets and All-Electric Vehicles that last for months and years instead of
hours and days.
Or, a super-charged and flexible as a Serta Mattress,
guaranteeing a shockingly good night’s rest!
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